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InChI:InChI=1/C3H6O/c1-3-2-4-3/h3H,2H2,1H3/t3-/m0/s1
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methyloxirane
(S)-1,2-Propanediol
(2R)-propane-1,2-diol
(S)-Propylene oxide
Conditions | Yield |
---|---|
With
(S,S)-[N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino]cobalt(III) acetate; water;
at 20 ℃;
for 14h;
|
46% |
With
water;
(R,R)-[Co(salen)]2*GaCl3;
at 20 ℃;
for 3h;
|
43% |
With
Aspergillus niger epoxide hydrolases immobilized onto modified Eupergit C;
In
aq. phosphate buffer; dimethyl sulfoxide;
at 25 ℃;
for 4h;
pH=6.5;
Reagent/catalyst;
pH-value;
enantioselective reaction;
Kinetics;
Enzymatic reaction;
|
43% 75.4 % ee |
methyloxirane
(S)-1,2-Propanediol
(S)-Propylene oxide
Conditions | Yield |
---|---|
With
C72H102Co2F12N4O12P2; water;
at 0 - 20 ℃;
for 2.5h;
optical yield given as %ee;
|
43% 50% |
With
(R,R)-N,N′-bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediaminocobalt(III) acetate;
In
water;
at 0 ℃;
for 14h;
Inert atmosphere;
|
45% 43% |
1-bromo-2(S)-hydroxypropane
propene
carbon tetrafluoride
2-chloro-1-propanol
(S) 1,1-diphenyl 1,3-dihydroxybutane
(S)-(+)-hept-4-yn-2-ol
Methyl 2-acetamidoacrylate
(S,S)-bis-(2-hydroxypropyl) sulphide
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