97-88-1

Product NameButyl methacrylate
Molecular FormulaC₈H₁₄O₂
Molecular Weight142.198
Purity99%
Appearanceclear colourless liquid with an ester-like odour

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CasNo： 97-88-1
Molecular Formula： C₈H₁₄O₂
Appearance： clear colourless liquid with an ester-like odour
Purity： 99%

Top Quality Chinese Manufacturer supply 97-88-1 Butyl methacrylate

Molecular Formula:C8H14O2
Molecular Weight:142.198
Appearance/Colour:clear colourless liquid with an ester-like odour
Vapor Pressure:2 mm Hg ( 20 °C)
Melting Point:-75 °C
Refractive Index:n20/D 1.423(lit.)
Boiling Point:160 °C at 760 mmHg
Flash Point:50.6 °C
PSA：26.30000
Density:0.894 g/cm³
LogP:1.90580

Butyl methacrylate(Cas 97-88-1) Usage

Production Methods	n-Butyl methacrylate is produced by the reaction of methacrylic acid or methyl methacrylate with butanol .
Air & Water Reactions	Flammable. Sensitive to moisture. Insoluble in water.
Reactivity Profile	Butyl methacrylate reacts exothermically with acids. Reacts with oxidizing agents. Strong oxidizing acids may cause a reaction that is sufficiently exothermic to ignite the reaction products. Heat is generated with caustic solutions. Generates flammable hydrogen with alkali metals and hydrides. Polymerizes easily .
Health Hazard	Inhalation may cause nausea because of offensive odor. Contact with liquid causes irritation of eyes and mild irritation of skin. Ingestion causes irritation of mouth and stomach.
Fire Hazard	Behavior in Fire: Containers may explode due to polymerization.
Chemical Reactivity	Reactivity with Water No reaction; Reactivity with Common Materials: No reactions; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: May occur upon exposure to heat; Inhibitor of Polymerization: 9-15 ppm monomethyl ether of hydroquinone; 90-120 ppm hydroquinone.
Safety Profile	Moderately toxic by intraperitoneal route. Mddly toxic by ingestion, inhalation, and skin contact. An experimental teratogen. Experimental reproductive effects. A skin irritant. Flammable liquid when exposed to heat or flame. Explosive in the form of vapor when exposed to heat or flame. Violent polymerization can be caused by heat, moisture, oxidizers. To fight fire, use foam, dry chemical, CO2. When heated to decomposition it emits acrid smoke and irritating fumes.
Potential Exposure	Forms an explosive mixture with air. Unless inhibitor is maintained at the proper level, oxidizers, heat, ultraviolet light, contamination, or moisture may cause polymerization. May accumulate static electrical charges and cause ignition of its vapors.
Shipping	UN2227 Butyl methacrylate, stabilized, Hazard Class: 3; Labels: 3—Flammable liquid.
Purification Methods	Purify as for butyl acrylate. [Beilstein 2 IV 1525.]
Incompatibilities	Forms an explosive mixture with air. Unless inhibitor is maintained at the proper level, oxidizers, heat, ultraviolet light, contamination, or moisture may cause polymerization. May accumulate static electrical charges and cause ignition of its vapors
General Description	A clear colorless liquid. Flash point 130°F. Less dense (7.5 lb / gal) than water and insoluble in water. Hence floats on water. Vapors heavier than air. Used to make resins adhesives, and oil additives.

InChI:InChI=1/C8H14O2/c1-4-6(2)5-7(3)8(9)10/h6H,3-5H2,1-2H3,(H,9,10)/p-1

97-88-1 Relevant articles

Silica-Supported MnII Sites as Efficient Catalysts for Carbonyl Hydroboration, Hydrosilylation, and Transesterification

Ghaffari, Behnaz,Mendes-Burak, Jorge,Chan, Ka Wing,Copéret, Christophe

supporting information, p. 13869 - 13873 (2019/11/11)

Manganese, the third most abundant trans...

Dehydrogenative Silylation of Alkenes for the Synthesis of Substituted Allylsilanes by Photoredox, Hydrogen-Atom Transfer, and Cobalt Catalysis

Yu, Wan-Lei,Luo, Yong-Chun,Yan, Lei,Liu, Dan,Wang, Zhu-Yin,Xu, Peng-Fei

supporting information, p. 10941 - 10945 (2019/07/17)

A synergistic catalytic method combining...

METHOD FOR THE PRODUCTION PROCESS OF METHACRYL ACID ESTER

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Paragraph 0044; 0045, (2017/06/02)

The present invention relates to a metho...

METHOD FOR THE PRODUCTION PROCESS OF BUTYL METHACRYLATE

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Paragraph 0028-0030, (2017/01/09)

The present invention relates to a prepa...

97-88-1 Process route

: 79-41-4,25087-26-7,50867-57-7
poly(methacrylic acid)

: 71-36-3
butan-1-ol

: 97-88-1,9003-63-8
2-methyl-butyl acrylate

Conditions

Conditions	Yield
sulfopolyphenylene ketone; at 140 ℃; under 3800 Torr; Kinetics; Product distribution; continuous process in stainless tube reactor; studied at various temperature and at different feed rates of the raw material;	97.3%
With titanium catalyst; at 115 ℃; for 1h;	92.11%
With sulfuric acid; hydroquinone; benzene;
With toluene-4-sulfonic acid; In benzene; Heating;
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; at 20 ℃;

: 80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7
methacrylic acid methyl ester

: 71-36-3
butan-1-ol

: 97-88-1,9003-63-8
2-methyl-butyl acrylate

Conditions

Conditions	Yield
With air; titanium(III) triisopropoxide; acetylacetone functionalised polymethylstyrene; chlorot; for 4h; Heating;	85%
With titanium catalyst; at 115 ℃; for 1h; Temperature;	71.03%
tetrabutoxytitanium; at 115 ℃; for 1h; Product distribution / selectivity;	63.8%
With sodium butanolate;
tetrabutoxytitanium; at 100 - 130 ℃; Industry scale;
With 10H-phenothiazine; 4-methoxy-phenol; at 115 ℃; flow conditions;
Industrial scale;
With tetrabutoxytitanium; TEMPOL; at 111 ℃; for 2h;	10.3 g
With tetrabutoxytitanium; TEMPOL; at 115 ℃; for 2h;
With 10H-phenothiazine; In water; at 115 ℃; Temperature;
at 64.5 - 91.9 ℃; Temperature; Concentration;
With sulfuric acid; at 115 ℃;
With Mn(II) supported on silica; at 80 ℃; for 24h; Reagent/catalyst; Glovebox; Inert atmosphere; Sealed tube;	96 %Spectr.